Hadith 809
Anas (May Allah be pleased with him) reported:
عن أنس رضى الله عنه قال: رخص رسول الله ، صلى الله عليه وسلم، للزبير وعبد الرحمن بن عوف رضى الله عنهما في لبس الحرير لحكة بهما.((متفق عليه))
The Messenger of Allah (ﷺ) permitted Zubair and `Abdur-Rahman bin `Auf (May Allah be pleased with them) to wear silk because they were suffering from an itch. [Al-Bukhari and Muslim].
In plain words
Though silk is normally not worn by men, the Prophet permitted two companions to wear it because of a skin ailment. A sign that genuine need can lift the usual restriction, with Allah's commands carrying mercy.
Reference : Riyad as-Salihin 809 In-book reference : Book 3, Hadith 32